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1.
In this study, the 14N:15N ratio of suspended particulate material collected from the Tamar river estuary, south-west England, is described. Three populations of particles, distinguishable by their 15N content, were observed. This investigation has shown that populations of estuarine particles are generated by biological transformations in situ and that the 15N content of estuarine particles does not merely reflect hydrodynamic mixing of the freshwater and seawater source particulate material.  相似文献   
2.
采用正交试验等方法对淮山提取液(DB-Ext)代替羧甲基纤维素钠(CMC)作为调配型酸奶稳定剂的效果进行了初步探讨。结果表明以原料的6.0倍水量在110℃的温度条件下,提取40min,所得的淮山提取液的粘度为3500mPa  相似文献   
3.
Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N2O to the atmosphere. Large and rapid increases in the concentrations of N2O, NO3?, and NO2? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N2O in rivers.  相似文献   
4.
Vertical measurements of NH4+, NO3? and N2O concentrations, NO3? and NH4+ uptake, and NH4+ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom NO3?N l?1 at the most strongly stratified station whereas NH4+ was relatively constant with depth at all stations (~0.1 μg-atom NH4+N l?1). The highest rates of NH4+ oxidation generally occurred in the near surface waters and decreased with depth. N2O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. NH4+ oxidation by nitrifying bacteria may account for about 30% of the total NH4+ utilization (i.e. bacterial+agal) and, assuming oxidation through to NO3?, may supply about 40% of the algal requirements of NO3? in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.  相似文献   
5.
The main reasons for the high content of inorganic N and its increase by several times in the Changjiang River and its mouth during the last 40 years were analysed in this work. The inorganic N in precipitation in the Changjiang River catchment mainly comes from gaseous loss of fertilizer N, N resulting from the increases of population and livestock, and from high temperature combustions of fossil fuels. N from precipitation is the first N source in the Changjiang River water and the only direct cause of high content of inorganic N in the Changjiang River and its mouth. The lost N in gaseous form and from agriculture non-point sources fertilizer comprised about 60% of annual consumption of fertilizer N in the Changjiang River catchment and were key factors controlling the high content of inorganic N in the Changjiang River mouth. The fate of the N in precipitation and other N sources in the Changjiang River catchment are also discussed in this paper.  相似文献   
6.
A new design is proposed for large (up to 6-m) liquid mirror containers. The design uses Kevlar, foam and aluminum, as in previous designs, but with a different configuration that makes the container lighter, stronger and more rigid. The results of finite element analysis are presented, consisting in the deformations due to temperature changes and to weight, and in the security factor for each material when maximum constraints are applied. Tilt rigidity is also analyzed. They show that the composite material construction technique gives a good performance up to 6 m diameters. The figures and tables contained in this paper can be used as recipes to build containers having diameters between 2 and 6 m. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
7.
杨红霞  刘崴  李冰 《岩矿测试》2008,27(6):405-408
建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。  相似文献   
8.
Experimental phase equilibrium and trace element partitioningdata are reported for H2O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO2 contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H2O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite  相似文献   
9.
渤海湾盆地新生界生油岩系底界面温度分布   总被引:3,自引:1,他引:2       下载免费PDF全文
依据渤海湾盆地2000余口测温井的地温梯度数据、地层岩性描述、分层数据以及钻井资料,计算了该盆地各生油岩系底界面的温度。统计结果表明:渤海湾盆地沙河街组大部分凹陷区地层底界面温度介于90℃至150℃,目前仍具有大量生油的温度条件,而在隆起或一些凸起地区,该地层组段温度普遍小于90℃,未能达到生油的温度指标。东营组和孔店组地层也仍具有一定的生油温度条件。研究还表明:地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷区地层界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。  相似文献   
10.
沸石强化过滤的中试及生产性试验研究   总被引:2,自引:0,他引:2  
对新型水处理材料沸石强化常规给水处理工艺进行了中试和生产性试验,并与石英砂滤料做了对比.中试结果表明粒径为0.80-1.20mm沸石对浊度、氨氮、有机物都表现出良好的去除效果,过滤时的水头损失、反冲洗强度明显小于石英砂,不仅能满足反冲洗要求,还可节省反冲洗水量,降低运行成本.在生产性试验条件下,沸石对浊度、氨氮、耗氧量的去除率分别为95%、83%和39%.因此,在当前水源水遭到污染的情况下,用沸石替代石英砂滤料可明显改善水质,在不增加处理构筑物的情况下,对给水处理工艺可起到强化作用  相似文献   
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